Azerbaijan National Academy of Sciences

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02.00.06

Chemistry of high-molecular compounds

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02.00.06

Chemistry of high-molecular compounds

Macroaroxyl radicals: regularities, synthesis, properties and ways of practical use

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Chemistry of macromolecules

-         number of scientific publications printed abroad

270

90

-   number of Doctors

The scientific bases of thermal, cation and anion polymerization of quinines and their copolymerization with some vinyl monomers have been developed, the kinetic regularities have been revealed and the mechanisms of these reactions have been proposed and also new generation of reactive polyfunctional polyconjugated high-molecular compounds has been created.

It has been shown that the phenols, naphthols, aminopheols, aromatic amines and diamines, oxyquinoline, amine- and oxypyridines undergo the oxidative polycondensation reaction in the presence of various oxidizers in relatively moderate conditions and form the soluble and melting polyfunctional polyconjugated homo- and cooligomers, including hydroxyl and amine groups.

The methods of preparation of stable macroaroxyl radicals on the basis of homo- and cooligomerization of hydroxyarylenes have been developed. It has been shown that in these systems a concentration of paramagnetic centers determines a density of localized states nearby Fermi equation on which an electric charge transfer is carried out.

2. Kasebi F.S., Gezaz S.M., Mamedov B.A. Preparation, acid curing and thermal stability of various formulated phenolic resole resins: Unfilled and nanocomposites,/ International journal of Polymeric Materials, London 2012, Vol.61, N 5, p. 323-340.

3. A.Valipour, P.Najafi Moghaddam B.A.Mamedov/ Synthesis of hydrophilic template as a matrix polymer for preparation of soluble conductive polyaniline composites/archives des science journal, Switzerland, Geneva 2012; vol.65, № 7, p. 14–20.

4. A.Valipour, P. N. Moghaddam , B.A. Mamedov. Some aspects of chemical procedures & application trends of polyaniline as an intrinsically conductive polymer, Life Sci J.2012; vol. 9 , № 4, p. 409–421.

5. A.Y.Valipour, P.N. Moghaddam, B.A. Mamedov /Recent advances in hybrid organicinorganic Conductive polyaniline Nano composites. Jokull journal ISSN:0449-0576. Reykjavik, Iceland, 2013.v. 2013,.issue July, p.211-251.

6. Б.А.Мамедов, Р.А.Ахмедова,С.С.Машаева, М.Ш.Гурбанов, A.М.Гулиев. Синтез полифункциональных полисопряженных олигомеров 4-аминофенола и использование их при создании антистатических композиционных материалов. Журнал «Прикладной Химии», 2013, Т.86, № 10, с.19.

7. Б.А.Мамедов Р.А.Ахмедова, С.С.Машаева, Д.Н.Алиева, Р.З.Шахназарли, А.М.Гулиев. Получение олиго-4-аминофенола и электропроводящих композиционных мaтериалов на его основе. “European applied sciences”, 2014, №1, 147-153

Diploma and gold medal of prize “Best Scientist Researcher – Patriot” of “European Publishing House” of AzerbaijanRepublic